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Sensors & Electronics

Chemical Sensors

Semi-Volatile Chemical Stability (226)

Problem: Need to understand the degradation and stability of important semi-volatile (and volatile) chemicals in the environment

Analytical Instrument Suite Graphic

Project Activity Scope (from Technical Overview Chart): Mechanisms through Sensors and Devices

PNNL Solution:

  • Develop specialized test chamber to evaluate chemical reactions in the atmosphere and on environmental media
  • Assemble instrumentation to determine chemical kinetics, degradation products and reaction rates
  • Determine stability of residual chemicals
  • Use to evaluate chemicals and sensors for specific application conditions

Capabilities Employed to Meet Client Needs: Design and fabrication of inert Teflon chamber (to minimize wall effects) and large-volume preconcentrator; UV-A simulation of sunlight O3, hydroxy radicals, and other reaction mechanisms; Analysis by GCMS, GC, long-path FTIR, UV photolysis, chemiluminescence particle counting and acoustic gas analysis.

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Contact: Jerome Birnbaum

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